Large negative cubic hyperpolarizability for the spin-crossover compound cis-bis(thiocyanato)bis[N-(2-pyridylmethylene)aminobiphenyl]iron(II) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 1997

Large negative cubic hyperpolarizability for the spin-crossover compound cis-bis(thiocyanato)bis[N-(2-pyridylmethylene)aminobiphenyl]iron(II)

Résumé

The first example of a spin-crossover iron(II) compound with a large negative third-order polarizability, associated with an instantaneous electronic response, is reported; magnetic measurements show that this compound, cis-bis(thio-cyanato)bis[N-(2-pyridylmethylene)aminobip henyl]iron(II), characterized by X-ray structural data is in the high-spin form at room temperature.

Dates et versions

hal-01550146 , version 1 (29-06-2017)

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Jean-François Letard, Sébastien Montant, Philippe Guionneau, Patrick Martin, Annie Lecalvez, et al.. Large negative cubic hyperpolarizability for the spin-crossover compound cis-bis(thiocyanato)bis[N-(2-pyridylmethylene)aminobiphenyl]iron(II). Chemical Communications, 1997, 8, pp.745-746. ⟨10.1039/A700019G⟩. ⟨hal-01550146⟩
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