4-Benzoylbenzoate intercalated in layered double hydroxides: A new catalyst for photo-oxidation of sulfides in solution and in the gas phase

Thierry Pigot (1) , T. Arbitre , Hervé Martinez (1) , Sylvie Lacombe-Lhoste (1)

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

A new mixed organic-inorganic photosensitizer, based on 4-benzoylbenzoate intercalated into a layered double hydroxide has been prepared, characterized and successfully tested for the photo-oxidation of dialkylsulfides, both in acetonitrile and in the gas phase.

Mots clés: sulfide; organic compound; Photooxidation; photosensitizing agent; catalyst; gas; hydroxide; inorganic compound; intercalation complex; Layered double hydroxide; benzoic acid derivative; acetonitrile; 4 benzoylbenzoate; 4-Benzoylbenzoate; unclassified drug

Domaines: Chimie; Matériaux

Thierry Pigot, T. Arbitre, Hervé Martinez, Sylvie Lacombe-Lhoste. 4-Benzoylbenzoate intercalated in layered double hydroxides: A new catalyst for photo-oxidation of sulfides in solution and in the gas phase. Tetrahedron Letters, 2004, 45 (21), pp.4047-4050. ⟨10.1016/j.tetlet.2004.03.149⟩. ⟨hal-01504002⟩