The electronic structure of the CuRh1-xMgxO 2 thermoelectric materials: An X-ray photoelectron spectroscopy study

T.K. Le (1) , Delphine Flahaut (1) , Hervé Martinez (1) , Nathalie Andreu (1) , Danielle Gonbeau (1) , E. Pachoud (2) , D. Pelloquin (2) , A. Maignan (2)

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux
2 CRISMAT - Laboratoire de cristallographie et sciences des matériaux

A detailed X-ray photoelectron spectroscopy study has been performed for the CuRh1-xMgxO2 (x=0, 0.04 and 0.10) series for a better understanding of the role of the Mg2 substitution on the electrical properties and the value of the Seebeck coefficient. This study is based on an analysis of different compounds such as Rh2O3, Sr2RhO4 and CuCrO2 in order to characterize different oxidation states (Rh3 and Rh4 in octahedral oxygen environment and Cu in a dumbbell OCuO coordination). The Cu2p signal of copper in the non-doped compounds CuCrO2 and CuRhO2 reveals different electronic structures. An evolution of the Cu2p core signal with the increase of Mg2 content in the CuRh1-xMg xO2 is highlighted by XPS. The differences observed, especially for the Cu2p core peaks are discussed for the non-doped compounds CuCrO2 and CuRhO2 as for the CuRh1-xMg xO2 series upon Mg2 substitution. © 2011 Elsevier Inc.

Mots clés: Delafossite; Rh3d; Thermoelectric properties; XPS

Domaines: Chimie; Matériaux

T.K. Le, Delphine Flahaut, Hervé Martinez, Nathalie Andreu, Danielle Gonbeau, et al.. The electronic structure of the CuRh1-xMgxO 2 thermoelectric materials: An X-ray photoelectron spectroscopy study. Journal of Solid State Chemistry, 2011, 184 (9), pp.2387-2392. ⟨10.1016/j.jssc.2011.07.005⟩. ⟨hal-01499432⟩