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Article Dans Une Revue Dyes and Pigments Année : 2015

Influence of the halogen atom on the solid-state fluorescence properties of 2-phenyl-benzoxazole derivatives

Résumé

Four halogenated derivatives of 2-phenyl-benzoxazole and the unsubstituted analogue were studied in solution and as powders by absorption and steady-state fluorescence spectroscopy. In solution, the fluorescence quantum yield was progressively decreased when increasing the size of the halogen atom, as explained by heavy atom effect. In the solid state, an increase in photoluminescence efficiency was observed when passing from the fluorinated to chlorinated derivative, and then the fluorescence efficiency was decreased for the brominated and iodinated derivatives, the latter compound being virtually not emissive. To explain the solid-state behavior, the influence of molecular arrangement on the emission properties was discussed on the basis of X-ray data. Finally, microcrystals were generated using a solvent-exchange method. An evolution from elongated platelets to cubic particles was observed with increasing the size of the halogen atom, providing preliminary information for the use of these compounds as micro- and nanomaterials.
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hal-01458708 , version 1 (09-02-2021)

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A. Ghodbane, Nathalie Saffon, Sylvie Blanc, Suzanne Fery-Forgues. Influence of the halogen atom on the solid-state fluorescence properties of 2-phenyl-benzoxazole derivatives. Dyes and Pigments, 2015, 113, pp.219-226. ⟨10.1016/j.dyepig.2014.08.011⟩. ⟨hal-01458708⟩
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