Melting behavior of mixed U-Pu oxides under oxidizing conditions

Abstract : In order to use mixed U-Pu oxide ceramics in present and future nuclear reactors, their physical and chemical properties need to be well determined. The behavior of stoichiometric (U,Pu)O-2 compounds is relatively well understood, but the effects of oxygen stoichiometry on the fuel performance and stability are often still obscure. In the present work, a series of laser melting experiments were carried out to determine the impact of an oxidizing atmosphere, and in consequence the departure from a stoichiometric composition on the melting behavior of six mixed uranium plutonium oxides with Pu content ranging from 14 to 62 wt%. The starting materials were disks cut from sintered stoichiometric pellets. For each composition we have performed two laser melting experiments in pressurized air, each consisting of four shots of different duration and intensity. During the experiments we recorded the temperature at the surface of the sample with a pyrometer. Phase transitions were qualitatively identified with the help of a reflected blue laser. The observed phase transitions occur at a systematically lower temperature, the lower the Pu content of the studied sample. It is consistent with the fact that uranium dioxide is easily oxidized at elevated temperatures, forming chemical species rich in oxygen, which melt at a lower temperature and are more volatile. To our knowledge this campaign is a first attempt to quantitatively determine the effect of O/M on the melting temperature of MOX. (C) 2016 Elsevier B.V. All rights reserved.
Type de document :
Article dans une revue
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Elsevier, 2016, 374, pp.125-128. 〈10.1016/j.nimb.2016.01.032〉
Liste complète des métadonnées

https://hal.archives-ouvertes.fr/hal-01435217
Contributeur : Im2np Bibliométrie <>
Soumis le : vendredi 13 janvier 2017 - 16:41:31
Dernière modification le : jeudi 14 juin 2018 - 15:26:35

Identifiants

Collections

Citation

Michal Strach, Dario Manara, Renaud C. Belin, Jacques Rogez. Melting behavior of mixed U-Pu oxides under oxidizing conditions. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Elsevier, 2016, 374, pp.125-128. 〈10.1016/j.nimb.2016.01.032〉. 〈hal-01435217〉

Partager

Métriques

Consultations de la notice

70