Accurate determination of I-129 concentrations and I-129/Cs-137 ratios in spent nuclear resins by Accelerator Mass Spectrometry

Emmanuelle Nottoli (1) , Philippe Bienvenu , Alexandre Labet , Didier Bourles (1) , Maurice Arnold (1) , Make Bertaux

1 CEREGE - Centre européen de recherche et d'enseignement des géosciences de l'environnement

Determining long-lived radionuclide concentrations in radioactive waste has fundamental implications for the long-term management of storage sites. This paper focuses on the measurement of low I-129 contents in ion exchange resins used for primary fluid purification in Pressurised Water Reactors (PWR). Iodine-129 concentrations were successfully determined using Accelerator Mass Spectrometry (AMS) following a chemical procedure which included (1) acid digestion of resin samples in HNO3/HClO4, (2) radioactive decontamination by selective iodine extraction using a new chromatographic resin (CL Resin), and (3) Agl precipitation. Measured I-129 concentrations ranged from 4 to 12 ng/g, i.e. from 0.03 to 0.08 Bq/g. The calculation of I-129/Cs-137 activity ratios used for routine waste management produced values in agreement with the few available data for PWR resin samples. (C) 2014 Elsevier Ltd. All rights reserved.

Mots clés: I-129; Accelerator mass spectrometry; PWR resin samples

Domaines: Sciences de l'environnement

Emmanuelle Nottoli, Philippe Bienvenu, Alexandre Labet, Didier Bourles, Maurice Arnold, et al.. Accurate determination of I-129 concentrations and I-129/Cs-137 ratios in spent nuclear resins by Accelerator Mass Spectrometry. Applied Radiation and Isotopes, 2014, 86, pp.90-96. ⟨10.1016/j.apradiso.2014.01.010⟩. ⟨hal-01426256⟩