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Article Dans Une Revue Coordination Chemistry Reviews Année : 2017

Lanthanide-based hexa-nuclear complexes and their use as molecular precursors.

Résumé

The use of lanthanide-based poly-nuclear complexes as molecular precursor for the design of extended molecular frameworks is still an innovative synthesis strategy. Oxo-hydroxo poly-nuclear complexes are generally obtained by controlling pH conditions during reaction process. After a short description of the lanthanide hydrolysis phenomenon and a non-exhaustive inventory of existing complexes with increasing nuclearity, the present review focuses on lanthanide-based hexa-nuclear oxo-hydroxo complexes. Their syntheses and crystal structures are described and their interest as building blocks for the design of new coordination compounds with unprecedented physical properties is highlighted.
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Dates et versions

hal-01419228 , version 1 (28-09-2017)

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Guillaume Calvez, François Le Natur, Carole Daiguebonne, Kevin Bernot, Yan Suffren, et al.. Lanthanide-based hexa-nuclear complexes and their use as molecular precursors.. Coordination Chemistry Reviews, 2017, 340, pp.134-153. ⟨10.1016/j.ccr.2016.12.004⟩. ⟨hal-01419228⟩
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