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Article Dans Une Revue ChemCatChem Année : 2015

Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes

Résumé

A simple catalytic method involving all-metal aromatic frameworks as precatalysts ensures an efficient route to (Z)-alkenes. Aromatic triangular palladium clusters were used to reduce internal alkynes without any trace of the formation of alkane side products. These trinuclear complexes provide a catalytic system that parallels the activity and selectivity of their best mononuclear peers, and the catalyst likely operates through complementary mechanisms.

Domaines

Chimie organique

Dates et versions

hal-01397967 , version 1 (16-11-2016)

Identifiants

Citer

Pierre-Alexandre Deyris, Tatiana Caneque, Yanlan Wang, Pascal Retailleau, Franca Bigi, et al.. Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes. ChemCatChem, 2015, 7 (20), pp.3266-3269. ⟨10.1002/cctc.201500729⟩. ⟨hal-01397967⟩
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