C60 Recognition from Extended Tetrathiafulvalene Bis-acetylide Platinum(II) Complexes

Guillaume Bastien (1) , Paul-Ionut Dron (1) , Manon Vincent (1) , David Canevet (1) , Magali Allain (1) , Sébastien Goeb (1) , Marc Sallé (1)

1 MOLTECH-Anjou

The favorable spatial organization imposed by the square planar 4,4′-di(tert-butyl)-2,2′-bipyridine (dbbpy) platinum(II) complex associated with the electronic and shape complementarity of π-extended tetrathiafulvalene derivatives (exTTF) toward fullerenes is usefully exploited to construct molecular tweezers, which display good affinities for C60.

Domaines: Chimie

Guillaume Bastien, Paul-Ionut Dron, Manon Vincent, David Canevet, Magali Allain, et al.. C60 Recognition from Extended Tetrathiafulvalene Bis-acetylide Platinum(II) Complexes. Organic Letters, 2016, 18 (22), pp.5856-5859. ⟨10.1021/acs.orglett.6b02915⟩. ⟨hal-01393747⟩