Improvement of adherence and anticorrosion properties of an epoxy-polyamide coating on steel by incorporation of an indole-3 butyric acid-modified nanomagnetite

Abstract : In this study, synthesized magnetite (Fe 3 O 4 ) nanoparticles were treated with a corrosion inhibitor, indole-3 butyric acid (IBA) and incorporated in an epoxy-polyamide coating. The coating was applied on a carbon steel substrate. For comparison, coatings with- out particles or with nontreated Fe 3 O 4 particles were also prepared. The IBA-modified nanomagnetite (IBA–Fe 3 O 4 ) was characterized by infrared spec- troscopy and Zeta potential measurements. The inhibitive action of IBA was shown by electrochemical measurements (polarization curves) performed for a bare carbon steel in 0.1 M NaCl solution containing Fe 3 O 4 or IBA–Fe 3 O 4 nanoparticles. Adherence and anticorrosion properties of the epoxy-based coatings containing Fe 3 O 4 or IBA–Fe 3 O 4 were compared to those of the pure epoxy-polyamide resin by dry and wet adherence measurements and by salt spray test. The results showed significant improvement of the film adherence and higher corrosion protection of the carbon steel in the presence of IBA–Fe 3 O 4 . It was concluded that the IBA effect was restricted to the metal/coating interface.
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Anh Truc Trinh, Thu Trang Nguyen, Thu Thuy Thai, Thi Xuan Hang To, Xuan Hoan Nguyen, et al.. Improvement of adherence and anticorrosion properties of an epoxy-polyamide coating on steel by incorporation of an indole-3 butyric acid-modified nanomagnetite. Journal of Coatings Technology and Research, Springer Verlag (Germany), 2016, vol. 13 (n° 3), pp. 489-499. ⟨10.1007/s11998-015-9768-y⟩. ⟨hal-01360664⟩

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