Monodisperse fluorene oligomers exhibiting strong dipolar coupling interactions

Rémi Anémian (1) , Jean-Christophe Mulatier (1) , Chantal Andraud (1) , Olivier Stéphan (2) , Jean-Claude Vial (2)

1 STIM - Stéréochimie et Interactions Moléculaires
2 LSP - Laboratoire de Spectrométrie Physique

Well-defined fluorene oligomers (n = 1 to 6) were prepared step by step using Suzuki and Yamamoto couplings, while absorption and photoluminescence properties evidenced very large dipolar coupling interactions between fluorene moieties.

Domaines: Catalyse; Matériaux; Chimie organique; Chimie inorganique

Rémi Anémian, Jean-Christophe Mulatier, Chantal Andraud, Olivier Stéphan, Jean-Claude Vial. Monodisperse fluorene oligomers exhibiting strong dipolar coupling interactions. Journal of the Chemical Society, Chemical Communications, 2002, 15, pp.1608-1609. ⟨10.1039/B201414A⟩. ⟨hal-01321632⟩