Combination of Pd/C and Amberlyst-15 in a single reactor for the acid/hydrogenating catalytic conversion of carbohydrates to 5-hydroxy-2,5-hexanedione

Fei Liu (1) , Maïté Audemar (1) , Karine de Oliveira Vigier (1) , Jean-Marc Clacens (2) , Floryan de Campo (2) , Jérôme François (1)

1 IC2MP [Poitiers] - Institut de chimie des milieux et matériaux de Poitiers [UMR 7285]
2 E2P2L - Eco-Efficient Products & Processes Laboratory

Here we show that combination of Pd/C and Amberlyst-15 in a single reactor allowed fructose and inulin to be converted to 5-hydroxy-2-5-hexanedione, a valuable chemical platform, in a one-pot process.

Domaines: Catalyse

Fei Liu, Maïté Audemar, Karine de Oliveira Vigier, Jean-Marc Clacens, Floryan de Campo, et al.. Combination of Pd/C and Amberlyst-15 in a single reactor for the acid/hydrogenating catalytic conversion of carbohydrates to 5-hydroxy-2,5-hexanedione . Green Chemistry, 2014, 16 ( 9 ), pp.4110-4114 ⟨10.1039/c4gc01158a⟩. ⟨hal-01320930⟩