Stratigraphy of a diamond epitaxial three-dimensional overgrowth using doping superlattices

F Lloret (1) , A Fiori (2) , D Araujo (1) , D. Eon (3) , M.P. Villar (1) , E. Bustarret (3)

1 Dpto. Ciencias de los Materiales, Universidad de Cadiz, Spain
2 NIMS - National Institute for Materials Science
3 NEEL - SC2G - Semi-conducteurs à large bande interdite

The selective doped overgrowth of 3D mesa patterns and trenches has become an essential fabrication step of advanced monolithic diamond-based power devices. A novel methodology is proposed here, combining the overgrowth of plasma-etched cylindrical mesa structures with the sequential growth of doping superlattices. The latter involve thin heavily boron doped epilayers separating thicker undoped epilayers in a periodic fashion. Beside the classical shape analysis under the scanning electron microscope relying on the appearance of facets corresponding to the main crystallographic directions and their evolution toward slow growing facets, the doping superlattices were used as markers in oriented cross-sectional lamellas prepared by Focused Ion Beam and observed by Transmission Electron Microscopy. This stratigraphic approach is shown here to be applicable to overgrown structures where faceting was not detectable. Intermediate growth directions were detected at different times of the growth process and the periodicity of the superlattice allowed to calculate the growth rates and parameters, providing an original insight into the planarization mechanism. Different configurations of the growth front were obtained for different sample orientations, illustrating the anisotropy of the 3D growth. Dislocations were also observed along the lateral growth fronts with two types of Burger vector: bsub01-1 = 1/2 [01-1] and bsub112 = 1/6 [112]. Moreover, the clustering of these extended defects in specific regions of the overgrowth prompted a proposal of two different dislocation generation mechanisms.

Mots clés: transmission electron microscopy; homoepitaxy; diamond

Domaines: Science des matériaux [cond-mat.mtrl-sci]

F Lloret, A Fiori, D Araujo, D. Eon, M.P. Villar, et al.. Stratigraphy of a diamond epitaxial three-dimensional overgrowth using doping superlattices. Applied Physics Letters, 2016, 108 (18), pp.181901. ⟨10.1063/1.4948373⟩. ⟨hal-01319640⟩