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The mechanism of inhibition by H-2 of H-2-evolution by hydrogenases

Abstract : By analysing the results of experiments carried out with two FeFe hydrogenases and several "channel mutants'' of a NiFe hydrogenase, we demonstrate that whether or not hydrogen evolution is significantly inhibited by H-2 is not a consequence of active site chemistry, but rather relates to H-2 transport within the enzyme.
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Vincent Fourmond, Carole Baffert, Kateryna Sybirna, Sebastien Dementin, Abbas Abou-Hamdan, et al.. The mechanism of inhibition by H-2 of H-2-evolution by hydrogenases. Chemical Communications, Royal Society of Chemistry, 2013, 49 (61), pp.6840 - 6842. ⟨10.1039/c3cc43297a⟩. ⟨hal-01268212⟩



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