Photoluminescence properties of core-shell SiO2/Lu2O3: Eu monodisperse heteronanoparticles
Résumé
Core-shell monodisperse heteroparticles of the composition SiO2/Lu1.86Eu0.14O3 have been synthesized using the developed technique for preparing spherical colloidal silicon dioxide particles with the size dispersion in the range 2.0-2.5% and the procedure for producing nanocoatings on the surface of spheres by codeposition. The structure of heteroparticles has been investigated, their excitation and photoluminescence spectra have been analyzed, and the lifetime of the (5) D (0) excited state of Eu3+ ions has been examined. It has been revealed that the luminescence decay time for heteroparticles increases by a factor of approximately two compared to that for a powdered luminophor Lu2O3: Eu (7 at %) prepared and treated under the same temperature conditions as the SiO2/Lu2O3: Eu (7 at %) heteroparticles. This effect has been attributed to the change in the effective refractive index and the local density of photon states in luminophor nanolayers of heteroparticles.