Molecular Propagation through small Avoided Crossings of Electron Energy Levels

Abstract : This is the second of two papers on the propagation of molecular wave packets through avoided crossings of electronic energy levels in a limit where the gap between the levels shrinks as the nuclear masses are increased. An earlier paper deals with the simplest two types of generic, minimal multiplicity avoided crossings, in which the levels essentially depend on only one of the nuclear configuration parameters. The present paper deals with propagation through the remaining four types of generic, minimal multiplicity avoided crossings, in which the levels depend on more than one nuclear configuration parameter.
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Submitted on : Tuesday, November 24, 2015 - 4:18:22 PM
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George Hagedorn, Alain Joye. Molecular Propagation through small Avoided Crossings of Electron Energy Levels. Reviews in Mathematical Physics, World Scientific Publishing, 1999, 11 (01), pp.41-101. ⟨10.1142/S0129055X99000040⟩. ⟨hal-01233198⟩

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