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A short route to cyclopentadienyl tricarbonylrhenium substituted derivatives

Abstract : CpRe(CO)(3) substituted derivatives were obtained in good yields (44-96%) from fulvenes and Re-2(CO)(10) in boiling mesitylene. This new methodology was applied to the synthesis of CpRe(CO)(3) substituted steroids with success. (C) 2002 Elsevier Science B.V. All rights reserved.
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Submitted on : Tuesday, May 11, 2021 - 10:28:07 AM
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F Le Bideau, J Henique, Pascal Pigeon, Jm Joerger, Siden Top, et al.. A short route to cyclopentadienyl tricarbonylrhenium substituted derivatives. Journal of Organometallic Chemistry, Elsevier, 2003, 668 (1-2), pp.140-144. ⟨10.1016/S0022-328X(02)02090-9⟩. ⟨hal-01230405⟩

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