Stalking Higher Energy Conformers on the Potential Energy Surface of Charged Species.

Vincent Brites (1) , Alvaro Cimas (1) , Riccardo Spezia (1) , Nicolas Sieffert (2) , J.T. Lisy (3) , Marie-Pierre Gaigeot (1)

1 LAMBE - Laboratoire Analyse et Modélisation pour la Biologie et l'Environnement
2 DCM - Département de Chimie Moléculaire
3 UIUC - University of Illinois at Urbana-Champaign [Urbana]

Combined theoretical DFT-MD and RRKM methodologies and experimental spectroscopic infrared predissociation (IRPD) strategies to map potential energy surfaces (PES) of complex ionic clusters are presented, providing lowest and high energy conformers, thresholds to isomerization, and cluster formation pathways. We believe this association not only represents a significant advance in the field of mapping minima and transition states on the PES but also directly measures dynamical pathways for the formation of structural conformers and isomers. Pathways are unraveled over picosecond (DFT-MD) and microsecond (RRKM) time scales while changing the amount of internal energy is experimentally achieved by changing the loss channel for the IRPD measurements, thus directly probing different kinetic and isomerization pathways. Demonstration is provided for Li(+)(H2O)3,4 ionic clusters. Nonstatistical formation of these ionic clusters by both direct and cascade processes, involving isomerization processes that can lead to trapping of high energy conformers along the paths due to evaporative cooling, has been unraveled.

Domaines: Chimie-Physique [physics.chem-ph]

Vincent Brites, Alvaro Cimas, Riccardo Spezia, Nicolas Sieffert, J.T. Lisy, et al.. Stalking Higher Energy Conformers on the Potential Energy Surface of Charged Species.. Journal of Chemical Theory and Computation, 2015, 11 (3), pp.871-883. ⟨10.1021/ct5008197⟩. ⟨hal-01219481⟩