A New FeMo Complex as a Model of Heterobimetallic Assemblies in Natural Systems: Mössbauer and Density Functional Theory Investigations

Solène Bouchard (1) , Martin Clémancey (2, 3) , Geneviève Blondin (2, 3) , Maurizio Bruschi (4, 5) , Kévin Charreteur (1) , Luca de Gioia (4) , Christine Leroy (1) , François Y. Pétillon (1) , Philippe P. Schollhammer (1) , Jean Talarmin (1)

1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
2 LCBM - UMR 5249 - Laboratoire de Chimie et Biologie des Métaux
3 LPCMB - Laboratoire de Physico-chimie des Métaux en Biologie
4 Dipartimento di Biotecnologie e Bioscienze
5 Département des Sciences de la Terre et de l'Environnement

The design of the new FeMo heterobimetallic species [FeMo(CO)(5)(kappa(2)-dppe)(mu-pdt)] is reported. Mossbauer spectroscopy and density functional theory calculations give deep insight into the electronic and structural properties of this compound.

Domaines: Chimie de coordination; Chimie inorganique

Solène Bouchard, Martin Clémancey, Geneviève Blondin, Maurizio Bruschi, Kévin Charreteur, et al.. A New FeMo Complex as a Model of Heterobimetallic Assemblies in Natural Systems: Mössbauer and Density Functional Theory Investigations. Inorganic Chemistry, 2014, 53 (21), pp.11345-11347. ⟨10.1021/ic501875q⟩. ⟨hal-01215528⟩