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Oxidative inactivation of NiFeSe hydrogenase

Abstract : We propose a resolution to the paradox that spectroscopic studies of NiFeSe hydrogenase have not revealed any major signal attributable to NiIII states formed upon reaction with O2, despite the fact that two inactive states are formed upon either aerobic or anaerobic oxidation.
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https://hal.archives-ouvertes.fr/hal-01211493
Contributor : Christophe Léger Connect in order to contact the contributor
Submitted on : Monday, October 5, 2015 - 11:28:56 AM
Last modification on : Tuesday, October 19, 2021 - 10:50:07 PM
Long-term archiving on: : Wednesday, January 6, 2016 - 10:34:37 AM

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Pierre Ceccaldi, Marta Marques, Vincent Fourmond, Inês Cardoso Pereira, Christophe Léger. Oxidative inactivation of NiFeSe hydrogenase. Chemical Communications, Royal Society of Chemistry, 2015, ⟨10.1039/C5CC05930E⟩. ⟨hal-01211493⟩

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