W. Lubitz, H. Ogata, O. Rüdiger, and E. Reijerse, Hydrogenases, Chemical Reviews, vol.114, issue.8, pp.4081-4148, 2014.
DOI : 10.1021/cr4005814

URL : https://hal.archives-ouvertes.fr/hal-00869039

A. Silakov, B. Wenk, E. Reijerse, and W. Lubitz, 14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge, Physical Chemistry Chemical Physics, vol.123, issue.16, pp.6592-6599, 2009.
DOI : 10.1039/b905841a

G. Caserta, S. Roy, M. Atta, V. Artero, M. Fontecave et al., Artificial hydrogenases: biohybrid and supramolecular systems for catalytic hydrogen production or uptake, Current Opinion in Chemical Biology, vol.25, pp.36-47, 2015.
DOI : 10.1016/j.cbpa.2014.12.018

URL : https://hal.archives-ouvertes.fr/hal-01166118

C. Van-dijk, A. Van-berkel-arts, and C. Veeger, strain Hildenborough and its oxygen stability, FEBS Letters, vol.1, issue.2, pp.340-344, 1983.
DOI : 10.1016/0014-5793(83)80525-0

C. Cavazza, Meynial-Salles, I.; Soucaille, P.; Fontecilla-Camps, J. C. C.; Guigliarelli, B

L. Yu, C. Greco, M. Bruschi, U. Ryde, L. De-gioia et al., Targeting Intermediates of [FeFe]-Hydrogenase by CO and CN Vibrational Signatures, Inorganic Chemistry, vol.50, issue.9, pp.3888-3900, 2011.
DOI : 10.1021/ic102039z

A. R. Finkelmann, M. T. Stiebritz, and M. Reiher, Activation Barriers of Oxygen Transformation at the Active Site of [FeFe] Hydrogenases, Inorganic Chemistry, vol.53, issue.22, pp.11890-11902, 2014.
DOI : 10.1021/ic501049z

D. Dogaru, S. Motiu, and V. Gogonea, . Thermodynamics and frontier molecular orbitals analyses, International Journal of Quantum Chemistry, vol.43, issue.16, pp.876-889, 2009.
DOI : 10.1002/qua.21875

URL : http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2613324

D. W. Mulder, E. S. Boyd, R. Sarma, R. K. Lange, J. A. Endrizzi et al., Stepwise [FeFe]-hydrogenase H-cluster assembly revealed in the structure of HydA??EFG, Nature, vol.276, issue.7295, pp.248-251, 2010.
DOI : 10.1093/bioinformatics/17.8.754

A. S. Pandey, T. V. Harris, L. J. Giles, J. W. Peters, and R. K. Szilagyi, Dithiomethylether as a Ligand in the Hydrogenase H-Cluster, Journal of the American Chemical Society, vol.130, issue.13, pp.4533-4540, 2008.
DOI : 10.1021/ja711187e

C. Lambertz, N. Leidel, K. G. Havelius, J. Noth, P. Chernev et al., O2 Reactions at the Six-iron Active Site (H-cluster) in [FeFe]-Hydrogenase, Journal of Biological Chemistry, vol.286, issue.47, pp.40614-40623, 2011.
DOI : 10.1074/jbc.M111.283648

C. Léger, S. Dementin, P. Bertrand, M. Rousset, and B. Guigliarelli, NiFe Hydrogenase Studied by Protein Film Voltammetry, Journal of the American Chemical Society, vol.126, issue.38, pp.12162-12172, 2004.
DOI : 10.1021/ja046548d

V. Fourmond, P. Infossi, M. Giudici-orticoni, P. Bertrand, and C. Léger, ???Two-Step??? Chronoamperometric Method for Studying the Anaerobic Inactivation of an Oxygen Tolerant NiFe Hydrogenase, Journal of the American Chemical Society, vol.132, issue.13, pp.4848-4857, 2010.
DOI : 10.1021/ja910685j

C. Greco, V. Fourmond, C. Baffert, P. Wang, S. Dementin et al., Combining experimental and theoretical methods to learn about the reactivity of gas-processing metalloenzymes, Energy Environ. Sci., vol.108, issue.11, pp.3543-3573, 2014.
DOI : 10.1039/C4EE01848F

URL : https://hal.archives-ouvertes.fr/hal-01211585

C. Baffert, K. Sybirna, P. Ezanno, T. Lautier, V. Hajj et al., Covalent Attachment of FeFe Hydrogenases to Carbon Electrodes for Direct Electron Transfer, Analytical Chemistry, vol.84, issue.18, pp.7999-8005, 2012.
DOI : 10.1021/ac301812s

URL : https://hal.archives-ouvertes.fr/hal-01268277

A. J. Bard and L. R. Faulkner, Electrochemical methods. Fundamental and applications. Third edition, 2004.

G. Goldet, C. Brandmayr, S. T. Stripp, T. Happe, C. Cavazza et al., Electrochemical Kinetic Investigations of the Reactions of [FeFe]-Hydrogenases with Carbon Monoxide and Oxygen: Comparing the Importance of Gas Tunnels and Active-Site Electronic/Redox Effects, Journal of the American Chemical Society, vol.131, issue.41, pp.14979-14989, 2009.
DOI : 10.1021/ja905388j

V. Hajj, C. Baffert, K. Sybirna, I. Meynial-salles, P. Soucaille et al., FeFe hydrogenase reductive inactivation and implication for catalysis, Energy Environ. Sci., vol.6, issue.2, pp.715-719, 2014.
DOI : 10.1039/C3EE42075B

URL : https://hal.archives-ouvertes.fr/hal-01481475