Low melting mixtures based on beta-cyclodextrin derivatives and N,N '-dimethylurea as solvents for sustainable catalytic processes

Jérôme François (1) , Michel Ferreira (2) , Herve Bricout (2) , Stephane Menuel (2) , Eric Monflier (2) , Sebastien Tilloy (2)

1 IC2MP [Poitiers] - Institut de chimie des milieux et matériaux de Poitiers [UMR 7285]
2 PRES Université Lille Nord de France

beta-Cyclodextrin series and N,N'-dimethylurea formed low melting mixtures able to immobilize organometallic species based on sulfonated phosphanes. Hydroformylation and Tsuji-Trost reactions were efficiently performed in these new solvents which led to new recyclable catalytic systems.

Domaines: Catalyse

Jérôme François, Michel Ferreira, Herve Bricout, Stephane Menuel, Eric Monflier, et al.. Low melting mixtures based on beta-cyclodextrin derivatives and N,N '-dimethylurea as solvents for sustainable catalytic processes. Green Chemistry, 2014, 16 (8), pp.3876-3880. ⟨10.1039/c4gc00591k⟩. ⟨hal-01186732⟩