Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Abstract : Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono-ligated complex has been demonstrated.
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Madanakrishna Katari, Eléonore Payen de la Garanderie, Edith Nicol, Vincent Steinmetz, Guillaume van der Rest, et al.. Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2015, 17 (39), pp.25689-25692. ⟨10.1039/C5CP01501D⟩. ⟨hal-01158292⟩

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