Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Physical Chemistry Chemical Physics Année : 2015

Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Résumé

Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono-ligated complex has been demonstrated.
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hal-01158292 , version 1 (31-12-2017)

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Madanakrishna Katari, Eléonore Payen de La Garanderie, Edith Nicol, Vincent Steinmetz, Guillaume G. van Der Rest, et al.. Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand. Physical Chemistry Chemical Physics, 2015, 17 (39), pp.25689-25692. ⟨10.1039/C5CP01501D⟩. ⟨hal-01158292⟩
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