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Rhodium-Catalyzed Cyclopropanation of Fluorinated Ole ns: A Straightforward Route to Highly Functionalized Fluorocyclopropanes

Abstract : An efficient access to highly functionalized monofluorocyclopropanes is described. The developed methodology allowed straightforward access to a large panel of polysubstituted fluorinated cyclopropanes in good to excellent yields and good diastereoselectivities. The Rh-catalyzed cyclopropanation proved to be efficient on several fluorinated olefins and several diazo compounds. This method represents the first general route to complex fluorinated cyclopropanes.
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https://hal.archives-ouvertes.fr/hal-01149632
Contributor : Madeleine Roux-Merlin <>
Submitted on : Thursday, May 7, 2015 - 1:51:27 PM
Last modification on : Wednesday, July 8, 2020 - 2:12:04 PM

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Amandine Pons, Hélène Beucher, Pavel Ivashkin, Gérald Lemonnier, Thomas Poisson, et al.. Rhodium-Catalyzed Cyclopropanation of Fluorinated Ole ns: A Straightforward Route to Highly Functionalized Fluorocyclopropanes. Organic Letters, American Chemical Society, 2015, 17 (7), pp.1790-1793. ⟨10.1021/acs.orglett.5b00576⟩. ⟨hal-01149632⟩

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