Raman spectroscopy of monohydrated l-asparagine up to 30GPa

J.A.F. Silva (1) , P.T.C. Freire (1) , J.A. Lima (1) , J. Mendes Filho (1) , F.E.A. Melo (1) , A.J.D. Moreno (2) , A. Polian (3)

1 Departamento de Física [Fortaleza]
2 UFMA - Universidade Federal do Maranhão = Federal University of Maranhão
3 IMPMC - Institut de minéralogie, de physique des matériaux et de cosmochimie

Amino acid crystals are important systems for investigating chemical bonds of biochemical interest. Raman spectroscopy was used to study the vibrational properties of monohydrated L-asparagine crystal submitted to high pressure. Under these conditions amino acids can undergo phase transition and, eventually, as is the case of L-alanine, transform to an amorphous phase. In this work monohydrated Lasparagine was submitted to pressures up to 30 GPa, twice the pressure for which L-alanine was observed to present the solid–amorphous phase transition. Up to the maximum pressure reached in the experiments, no evidence of amorphization was found in the present work. However, several modifications in the entire spectral range of the Raman spectrum (30–3600 cm1) suggest monohydrated L-asparagine undergoes a solid–solid phase transition at 10 GPa. The reversibility of the phase transition as well as the behavior of bands associated with hydrogen bond is also given.

Mots clés: Raman spectroscopy; High pressure; Phase transition

Domaines: Physique [physics]

J.A.F. Silva, P.T.C. Freire, J.A. Lima, J. Mendes Filho, F.E.A. Melo, et al.. Raman spectroscopy of monohydrated l-asparagine up to 30GPa. Vibrational Spectroscopy, 2015, 77, pp.35-39. ⟨10.1016/j.vibspec.2015.02.006⟩. ⟨hal-01121098⟩