Building a Lewis Acidic Phosphorus

Abstract : Using the σ- and п-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe3, H2O and MeOH.
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Submitted on : Thursday, December 18, 2014 - 10:41:18 AM
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Madelin Qin Yi Tay, Yunpeng Lu, Rakesh Ganguly, Gilles Frison, Louis Ricard, et al.. Building a Lewis Acidic Phosphorus. Phosphorus, Sulfur, and Silicon and the Related Elements, Taylor & Francis, 2015, 190, pp.785-788. ⟨10.1080/10426507.2014.980413⟩. ⟨hal-01096741⟩



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