K. Benzerara, N. Menguy, N. R. Banerjee, T. Tyliszczak, G. E. Brown et al., Alteration of submarine basaltic glass from the Ontong Java Plateau: A STXM and TEM study, Earth and Planetary Science Letters, vol.260, issue.1-2, pp.187-200, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00289834

H. Bluhm, K. Andersson, T. Araki, K. Benzerara, G. E. Brown et al., Soft X-ray microscopy and spectroscopy at the molecular environmental science beamline at the Advanced Light Source, Journal of Electron Spectroscopy and Related Phenomena, vol.150, issue.2-3, pp.86-104, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00020112

J. Buffle, F. L. Greter, and W. Haerdi, Measurement of complexation properties of humic and fulvic acids in natural waters with lead and copper ion-selective electrodes, Analytical Chemistry, vol.49, issue.2, pp.216-222, 1977.

J. Buffle, K. J. Wilkinson, S. Stoll, M. Filella, and J. Zhang, A Generalized Description of Aquatic Colloidal Interactions: The Three-colloidal Component Approach, Environmental Science & Technology, vol.32, issue.19, pp.2887-2899, 1998.

J. J. Dynes, T. Tyliszczak, T. Araki, J. R. Lawrence, G. D. Swerhone et al., Speciation and Quantitative Mapping of Metal Species in Microbial Biofilms Using Scanning Transmission X-ray Microscopy, Environmental Science & Technology, vol.40, issue.5, pp.1556-1565, 2006.

, Speciation and Quantitative Mapping of Metal Species in Microbial Biofilms Using Scanning Transmission X-ray Microscopy, Environ Sci Techno, vol.40, pp.1556-1565

G. Falkenberg, O. Clauss, A. Swiderski, and T. H. Tschentscher, Upgrade of the x-ray fluorescence beamline at HASYLAB/DESY, X-Ray Spectrometry, vol.30, issue.3, pp.170-173, 2001.

M. Filella, V. Chanudet, S. Philippo, and F. Quentel, Particle size and mineralogical composition of inorganic colloids in waters draining the adit of an abandoned mine, Goesdorf, Luxembourg, Applied Geochemistry, vol.24, issue.1, pp.52-61, 2009.
URL : https://hal.archives-ouvertes.fr/hal-01578069

D. Fortin and S. Langley, Formation and occurrence of biogenic iron-rich minerals, Earth-Science Reviews, vol.72, issue.1-2, pp.1-19, 2005.

A. Hitchcock, Chemical mapping with soft X-ray spectromicroscopy, Amer Lab, vol.33, pp.30-36, 2001.

B. D. Honeyman and P. H. Santschi, Metals in aquatic systems, Environmental Science & Technology, vol.22, issue.8, pp.862-871, 1988.

J. Houhou, B. S. Lartiges, A. Hofmann, G. Frappier, J. Ghanbaja et al., Phosphate dynamics in an urban sewer: A case study of Nancy, France, Water Research, vol.43, issue.4, pp.1088-1100, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00413475

M. P. Isaure, A. Laboudigue, A. Manceau, G. Sarret, C. Tiffreau et al., Quantitative Zn speciation in a contaminated dredged sediment by ?-PIXE, ?-SXRF, EXAFS spectroscopy and principal component analysis, Geochimica et Cosmochimica Acta, vol.66, issue.9, pp.1549-1567, 2002.
URL : https://hal.archives-ouvertes.fr/hal-01556363

. Jacobsen, . Wirick, . Flynn, and . Zimba, Soft X-ray spectroscopy from image sequences with sub-100 nm spatial resolution, Journal of Microscopy, vol.197, issue.2, pp.173-184, 2000.

L. Jeanneau, P. Faure, and E. Montarges-pelletier, Evolution of the source apportionment of the lipidic fraction from sediments along the Fensch River, France: A multimolecular approach, Science of The Total Environment, vol.398, issue.1-3, pp.96-106, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00329795

L. Jeanneau, P. Faure, E. Montarges-pelletier, and M. Ramelli, Impact of a highly contaminated river on a more important hydrologic system: Changes in organic markers, Science of The Total Environment, vol.372, issue.1, pp.183-192, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00163572

M. G. Kelly and B. A. Whitton, The Trophic Diatom Index: a new index for monitoring eutrophication in rivers, Journal of Applied Phycology, vol.7, issue.4, pp.433-444, 1995.

M. Lerotic, C. Jacobsen, J. B. Gillow, A. J. Francis, S. Wirick et al., Cluster analysis in soft X-ray spectromicroscopy: Finding the patterns in complex specimens, Journal of Electron Spectroscopy and Related Phenomena, vol.144-147, pp.1137-1143, 2005.

M. Lerotic, C. Jacobsen, T. Schäfer, and S. Vogt, Cluster analysis of soft X-ray spectromicroscopy data, Ultramicroscopy, vol.100, issue.1-2, pp.35-57, 2004.

E. M. Logan, I. D. Pulford, G. T. Cook, and A. B. Mackenzie, Complexation of Cu2+ and Pb2+ by peat and humic acid, European Journal of Soil Science, vol.48, issue.4, pp.685-696, 1997.

D. Mavrocordatos, D. Perret, and G. G. Leppard, Strategies and Advances in the Characterisation of Environmental Colloids by Electron Microscopy Denis Mavrocordatos, Environmental Colloids and Particles, vol.10, pp.345-404, 2007.

J. F. Mccarthy and J. M. Zachara, ES&T Features: Subsurface transport of contaminants, Environmental Science & Technology, vol.23, issue.5, pp.496-502, 1989.

L. C. Maclean, S. Beauchemin, and P. E. Rasmussen, Lead Speciation in House Dust from Canadian Urban Homes Using EXAFS, Micro-XRF, and Micro-XRD, Environmental Science & Technology, vol.45, issue.13, pp.5491-5497, 2011.

J. Miot, K. Benzerara, G. Morin, A. Kappler, S. Bernard et al., Iron biomineralization by anaerobic neutrophilic iron-oxidizing bacteria, Geochimica et Cosmochimica Acta, vol.73, issue.3, pp.696-711, 2009.

S. Mitsunobu, F. Shiraishi, H. Makita, B. N. Orcutt, S. Kikuchi et al., Bacteriogenic Fe(III) (Oxyhydr)oxides Characterized by Synchrotron Microprobe Coupled with Spatially Resolved Phylogenetic Analysis, Environmental Science & Technology, vol.46, issue.6, pp.3304-3311, 2012.

F. Bacteriogenic, III) (oxyhydr)oxides characterized by synchrotron microprobe coupled with spatially resolved phylogenetic analysis, Environ Sci Technol, vol.46, pp.3304-3311

E. Montarges-pelletier, L. Jeanneau, P. Faure, I. Bihannic, O. Barres et al., The junction of Fensch and Moselle rivers, France; mineralogy and composition of river materials, Environmental Geology, vol.53, issue.1, pp.85-102, 2007.

E. M. Murphy and J. M. Zachara, The role of sorbed humic substances on the distribution of organic and inorganic contaminants in groundwater, Geoderma, vol.67, issue.1-2, pp.103-124, 1995.

G. Olivié-lauquet, T. Allard, M. Benedetti, and J. P. Muller, Chemical distribution of trivalent iron in riverine material from a tropical ecosystem: a quantitative EPR study, Water Research, vol.33, issue.11, pp.2726-2734, 1999.

J. Osan, S. Török, B. Alföldy, and G. Falkenberg, Characterization of anthropogenic sediment particles after a transboundary water pollution of river Tisza using synchrotron radiation, 2004.

C. Priadi, P. Le-pape, G. Morin, S. Ayrault, F. Maillot et al., X-ray Absorption Fine Structure Evidence for Amorphous Zinc Sulfide as a Major Zinc Species in Suspended Matter from the Seine River Downstream of Paris, Ile-de-France, France, Environmental Science & Technology, vol.46, issue.7, pp.3712-3720, 2012.

J. Raabe, G. Tzvetkov, U. Flechsig, M. Böge, A. Jaggi et al., PolLux: A new facility for soft x-ray spectromicroscopy at the Swiss Light Source, Review of Scientific Instruments, vol.79, issue.11, p.113704, 2008.

H. Ade, D. Kilcoyne, T. Tyliszczak, R. H. Fink, and C. Quitmann, PolLux: A new facility for soft xray spectromicroscopy at the Swiss Light Source, Rev Sci Instrum, vol.79, p.113704, 2008.

C. Rivard, E. Montargès-pelletier, D. Vantelon, M. Pelletier, C. Karunakaran et al., Combination of multi-scale and multi-edge X-ray spectroscopy for investigating the products obtained from the interaction between kaolinite and metallic iron in anoxic conditions at 90 °C, Physics and Chemistry of Minerals, vol.40, issue.2, pp.115-132, 2012.
URL : https://hal.archives-ouvertes.fr/hal-01119588

, Journal of Physical Chemistry, vol.40, issue.1, pp.132-132, 1936.

J. Rose, A. Vilge, G. Olivie-lauquet, A. Masion, C. Frechou et al., Iron speciation in natural organic matter colloids, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.136, issue.1-2, pp.11-19, 1998.
URL : https://hal.archives-ouvertes.fr/hal-02377344

P. Santschi, P. Höhener, G. Benoit, and M. Buchholtz-ten-brink, Chemical processes at the sediment-water interface, Marine Chemistry, vol.30, pp.269-315, 1990.

U. Schwertmann and R. M. Taylor, Iron Oxides, SSSA Book Series, vol.1, pp.379-438, 2018.

M. M. Shafer, J. T. Overdier, J. P. Hurley, D. Armstrong, and D. Webb, The influence of dissolved organic carbon, suspended particulates, and hydrology on the concentration, partitioning and variability of trace metals in two contrasting Wisconsin watersheds (U.S.A.), Chemical Geology, vol.136, issue.1-2, pp.71-97, 1997.

W. Stumm, Aquatic colloids as chemical reactants: surface structure and reactivity, Colloids in the Aquatic Environment, vol.73, pp.1-18, 1993.

W. Stumm and J. J. Morgan, Aquatic chemistry: chemical equilibria and rates in natural waters, JL Schnoor and A Zehnder, p.p, 1022.

A. Tessier, F. Rapin, and R. Carignan, Trace metals in oxic lake sediments: possible adsorption onto iron oxyhydroxides, Geochimica et Cosmochimica Acta, vol.49, issue.1, pp.183-194, 1985.

E. C. Todd, D. M. Sherman, and J. A. Purton, Surface oxidation of chalcopyrite (CuFeS2) under ambient atmospheric and aqueous (pH 2-10) conditions: Cu, Fe L- and O K-edge X-ray spectroscopy, Geochimica et Cosmochimica Acta, vol.67, issue.12, pp.2137-2146, 2003.

G. Van-der-laan and I. W. Kirkman, The 2p absorption spectra of 3d transition metal compounds in tetrahedral and octahedral symmetry, J Phys Condens Matter, vol.4, pp.4189-4205, 1992.

L. A. Warren and E. A. Haack, Biogeochemical controls on metal behaviour in freshwater environments, Earth-Science Reviews, vol.54, issue.4, pp.261-320, 2001.

L. A. Warren and A. P. Zimmermann, Suspended particulate grain size dynamics and their implications for trace metal sorption in the Don River, Aquatic Sciences, vol.56, issue.4, pp.348-362, 1994.

G. A. Waychunas, C. S. Kim, and J. F. Banfield, Nanoparticulate Iron Oxide Minerals in Soils and Sediments: Unique Properties and Contaminant Scavenging Mechanisms, Journal of Nanoparticle Research, vol.7, issue.4-5, pp.409-433, 2005.

T. H. Yoon, S. B. Johnson, K. Benzerara, C. S. Doyle, T. Tyliszczak et al., In Situ Characterization of Aluminum-Containing Mineral?Microorganism Aqueous Suspensions Using Scanning Transmission X-ray Microscopy, Langmuir, vol.20, issue.24, pp.10361-10366, 2004.