A new ternary ruthenium(III) complex with 1,3-bis(salicylideneamino) propan-2-ol and 3-picolylamine: Synthesis, characterization, density functional theory and preparation of electrochemical sensor for nitrite analysis.

Achour Terbouche (1, 2) , Chafia Ait-Ramdane-Terbouche (1, 2) , Safia Djebbar (1) , Djamila Guerniche (2, 3) , Radia Bagtache (3) , Nour El Houda Bensiradj (4) , Amar Saal (4) , Didier Hauchard (5)

1 Laboratoire d'hydrométallurgie et chimie inorganique moléculaire
2 CRAPC - Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques
3 Laboratoire d'Electrochimie-Corrosion, Métallurgie et Chimie Minérale
4 LPCTCI - Laboratoire de Physico Chimie Théorique et Chimie Informatique
5 ISCR - Institut des Sciences Chimiques de Rennes

A novel electrochem. sensor based on graphite (G) functionalised with a new ternary ruthenium(III) complex was developed and applied to detect nitrite in aq. soln. The Ru(III) complex was synthesized using 1,3-bis(salicylideneamino) propan-2-ol polydentate Schiff base (BSAP) and 3-Picolylamine (PLA), and was characterized by elemental anal., Fourier transform IR spectroscopy (FT-IR), UV-visible spectrophotometry (UV-Visible), gradient-assisted hetero nuclear single quantum coherence spectroscopy (gHSQC) and cyclic voltammetry technique. In addn., the structure of the synthesized complex was optimized using d. functional theory (DFT). The results showed that the ternary Ru(III)-BSAP-PLA complex was formed and the adapted structure was an tetrahedral geometry.The electrochem. behavior of nitrite at the sensor prepd. using G/Ru(III)-BSAP-PLA composite shows that the evaluated electron transfer coeff. (α = 0.83) indicates a very significant electrocatalytic mechanism for oxidn. of nitrite in the presence of the Ru(III)-BSAP-PLA complex.Comparing to other published works, the sensor developed using G/Ru(III)-BSAP-PLA exhibited low limit of detection (LOD = 1.81 μM) around pH = 7. [on SciFinder(R)]

Mots clés: Ruthenium(III) complex; Characterization; DFT calculation; Electrochemical sensor

Domaines: Génie chimique; Génie des procédés

Achour Terbouche, Chafia Ait-Ramdane-Terbouche, Safia Djebbar, Djamila Guerniche, Radia Bagtache, et al.. A new ternary ruthenium(III) complex with 1,3-bis(salicylideneamino) propan-2-ol and 3-picolylamine: Synthesis, characterization, density functional theory and preparation of electrochemical sensor for nitrite analysis.. Journal of Molecular Structure, 2014, 1076, pp.501--511. ⟨10.1016/j.molstruc.2014.08.013⟩. ⟨hal-01069488⟩