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Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.

Abstract : A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl](+) proceeds through proton-coupled electron transfer steps.
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https://hal.archives-ouvertes.fr/hal-01069157
Contributor : Vincent Artero <>
Submitted on : Sunday, September 28, 2014 - 2:32:49 PM
Last modification on : Thursday, July 9, 2020 - 9:43:16 AM

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Sigolène Canaguier, Vincent Fourmond, Carlo U Perotto, Jennifer Fize, Jacques Pécaut, et al.. Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.. Chemical Communications, Royal Society of Chemistry, 2013, 49 (44), pp.5004-6. ⟨10.1039/c3cc40987b⟩. ⟨hal-01069157⟩

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