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Journal articles

Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.

Sigolène Canaguier 1 Vincent Fourmond 1 Carlo U Perotto 1 Jennifer Fize 1 Jacques Pécaut 2 Marc Fontecave 1, 3 Martin J Field 4 Vincent Artero 1 
1 LCBM - UMR 5249 - Laboratoire de Chimie et Biologie des Métaux
2 RICC - Reconnaissance Ionique et Chimie de Coordination
SYMMES - SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé : DRF/INAC/SYMMES
3 Chaire Chimie des processus biologiques
LCPB - Laboratoire de Chimie des Processus Biologiques
4 IBS - UMR 5075 - Institut de biologie structurale
Abstract : A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl](+) proceeds through proton-coupled electron transfer steps.
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https://hal.archives-ouvertes.fr/hal-01069157
Contributor : Vincent Artero Connect in order to contact the contributor
Submitted on : Sunday, September 28, 2014 - 2:32:49 PM
Last modification on : Saturday, June 25, 2022 - 8:27:26 PM

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CEA | CNRS | CDF | INAC-SCIB | IRTSV-CBM | LCPB | IBS | IBS-DYC | INC-CNRS | PSL | CEA-DRF | SORBONNE-UNIVERSITE | IRIG | CEA-GRE | SU-SCIENCES | SYMMES

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Sigolène Canaguier, Vincent Fourmond, Carlo U Perotto, Jennifer Fize, Jacques Pécaut, et al.. Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.. Chemical Communications, Royal Society of Chemistry, 2013, 49 (44), pp.5004-6. ⟨10.1039/c3cc40987b⟩. ⟨hal-01069157⟩

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