Effect of Industrial By-products Fillers on the Properties of Blended Cements in Sulphate Environments
Résumé
In previous studies, we have investigated the durability of normal concrete in various sulphates environments. The contribution of this study is the addition of industrial by-products fillers: granulated blast furnace slag and marble powder. These two fillers do not need any calorific energy compared to clinker manufacturing. From an environmental perspective, no more carbon dioxide is produce when these two materials are used. Furthermore, slag and powder marble are waste that should be stocked in adapted landfills. Samples of normal mortar were exposed for 12 months to two sulphate environments: ammonium sulphate and sulphuric acid at two concentrations (0.05 and 0.25 mol/L). The evolution of crystalline phases is analyzed by XRD and minerals are observed by SEM, microanalysis (EDS linked to SEM) confirms their chemical composition. These determinations involve both the superficial formations that internal training due to conservation bath. For a low concentration of suphate (0.05 mol/L), the results show that the crystalline phases of cement (CSH, CH, ettringite) seem unaffected in the interior of the sample where the sulphur is completely absent. On the other hand, the ammonium sulphate penetrates deeper (4mm) to a high concentration (0.25 mol/L). However in the case of attack by sulphuric acid, samples develop a dense surface gypsum deposit. The mechanical strength, including bending strength to be known very sensitive to surface, is important to study this durability.
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