Novel C1-symmetric dibenzophosphole ligands: application in hydroformylation reactions

Abdelouahd Oukhrib (1, 2) , Laurence Bonnafoux (3) , Armen Panossian (3) , Sandrine Waifang (1) , Duc Hanh Nguyen (1) , Martine Urrutigoity (1) , Françoise Colobert (3) , Maryse Gouygou (1) , Frédéric R. Leroux (3)

1 LCC - Laboratoire de chimie de coordination
2 Laboratoire de chimie des substances naturelles
3 LCM - Laboratoire de chimie moléculaire

A new family of non-symmetrical disubstituted dibenzophospholes possessing different steric and electronic effects have been synthesized and characterized. Their preliminary evaluation in rhodium-catalyzed hydroformylation reactions is presented.

Domaines: Chimie de coordination; Catalyse

Abdelouahd Oukhrib, Laurence Bonnafoux, Armen Panossian, Sandrine Waifang, Duc Hanh Nguyen, et al.. Novel C1-symmetric dibenzophosphole ligands: application in hydroformylation reactions. Tetrahedron, 2014, 70 (7), pp.1431-1436. ⟨10.1016/j.tet.2014.01.003⟩. ⟨hal-00992450⟩