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Article Dans Une Revue Chemistry - A European Journal Année : 2014

A direct, modular, and efficient construction of the P-C-P structural motif through coupling of manganese carbyne complexes with phosphines

Résumé

Easily available carbyne complexes of manganese were used as a source of carbyne fragments in an unconventional synthesis of backbone-substituted diphosphinomethanes and cyclic P-ylides upon coupling with secondary or tertiary phosphines, respectively, followed by demetalation under mild conditions.

Dates et versions

hal-00992333 , version 1 (16-05-2014)

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Citer

D.A. Valyaev, S. Bastin, K.I. Utegenov, Noël Lugan, Guy Lavigne, et al.. A direct, modular, and efficient construction of the P-C-P structural motif through coupling of manganese carbyne complexes with phosphines. Chemistry - A European Journal, 2014, 20 (8), pp.2175-2178. ⟨10.1002/chem.201304239⟩. ⟨hal-00992333⟩
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