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Article Dans Une Revue Inorganic Chemistry Année : 2009

A Mn-17 Octahedron with a Giant Ground-State Spin: Occurrence in Discrete Form and as Multidimensional Coordination Polymers

Résumé

A [(Mn11Mn6II)-Mn-III(mu(4)-O)(8)(mu(3)-L)(4)](25+) (L = N-3(-) or OCN-) octahedral unit is reported, occurring within 1 D (1)(infinity) and 2D (2)(infinity) coordination polymers, as well as the corresponding OD discrete cluster 3. It possesses a giant ground-state spin value, determined in the case of 3 to be S = 37, the second largest to be reported to date. In addition, compound 3 displays single-molecule magnet (SMM) behavior, and is thus the largest-spin SMM.
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hal-00982143 , version 1 (23-04-2014)

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Eleni E. Moushi, Theocharis C. Stamatalos, Wolfgang Wernsdorfer, Vassilios Nastopoulos, George Christou, et al.. A Mn-17 Octahedron with a Giant Ground-State Spin: Occurrence in Discrete Form and as Multidimensional Coordination Polymers. Inorganic Chemistry, 2009, 48 (12), pp.5049-5051. ⟨10.1021/ic801795x⟩. ⟨hal-00982143⟩

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