Phosphoryl Group as a Strong σ-Donor Anionic Phosphine-Type Ligand: A Combined Experimental and Theoretical Study on Long-Lived Room Temperature Luminescence of the [Ru(tpy)(bpy)(Ph2PO)]+ Complex

Emilie Lebon Tailhades (1) , Remy Sylvain (1) , Rémi E. Piau (2) , Cloé Lanthony (2) , Julien Pilmé (3) , Pierre Sutra (1) , Martial Boggio-Pasqua (2) , Jean-Louis Heully (2) , Fabienne Alary (2) , Alberto Juris (4) , Alain Igau (1)

1 LCC - Laboratoire de chimie de coordination
2 PTC - Photochimie théorique et computationnelle (LCPQ)
3 LCT - Laboratoire de chimie théorique
4 Dipartimento di Chimica "G. Ciamician"

Emilie Lebon Tailhades, Remy Sylvain, Rémi E. Piau, Cloé Lanthony, Julien Pilmé, et al.. Phosphoryl Group as a Strong σ-Donor Anionic Phosphine-Type Ligand: A Combined Experimental and Theoretical Study on Long-Lived Room Temperature Luminescence of the [Ru(tpy)(bpy)(Ph2PO)]+ Complex. Inorganic Chemistry, 2014, 53 (4), pp.1946-1948. ⟨10.1021/ic4028496⟩. ⟨hal-00981418⟩