A heterotrimetallic 3d-3d '-4f single chain magnet constructed from anisotropic high-spin 3d-4f nodes and paramagnetic spacers

Ruxandra Gheorghe (1) , Augustin M. Madalan (2) , Jean- Pierre Costes (3) , Wolfgang Wernsdorfer (4) , Marius Andruh (1)

1 Inorganic Chemistry Laboratory-Faculty of Chemistry
2 CIMMA - Chimie, Ingénierie Moléculaire et Matériaux d'Angers
3 LCC - Laboratoire de chimie de coordination
4 NEEL - QuantECA - Circuits électroniques quantiques Alpes

By connecting [LCuTb](3+) nodes with [Fe(CN)(6)](3-) spacers a 1-D coordination polymer with slow relaxation of magnetization is obtained (L(2-) is the N, N'-propylene-bis(3-methoxy-salicylideneiminato) anion).

Domaines: Physique [physics]

Ruxandra Gheorghe, Augustin M. Madalan, Jean- Pierre Costes, Wolfgang Wernsdorfer, Marius Andruh. A heterotrimetallic 3d-3d '-4f single chain magnet constructed from anisotropic high-spin 3d-4f nodes and paramagnetic spacers. Dalton Transactions, 2010, 39 (20), pp.4734-4736. ⟨10.1039/B925636A⟩. ⟨hal-00981380⟩