Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations

Dao-Peng Zhang , Li-Fang Zhang , Y.T. Chen , Hail L. Wang , Zhong-H. Ni , Wolfgang Wernsdorfer (1) , Jianz A. Jiang

1 NEEL - QuantECA - Circuits électroniques quantiques Alpes

Two cyanide-bridged alternated 1 : 1 Ru(III)/Mn(III) complexes structurally characterized as single-chain containing co-crystallized bulk anions and cations have been successfully assembled from [Mn(TPP)(H(2)O)(2)](+) and [Ru(acac)(2)(CN)(2)](-) blocks. Systematic investigation of their magnetic properties reveals typical single-chain magnet (SCM) behaviors for both of them

Domaines: Physique [physics]

Dao-Peng Zhang, Li-Fang Zhang, Y.T. Chen, Hail L. Wang, Zhong-H. Ni, et al.. Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations. Chemical Communications, 2010, 46 (20), pp.3550-3552. ⟨10.1039/B926710G⟩. ⟨hal-00979754⟩