Pincer versus Pseudo-Pincer: Isomerism in Palladium(II) Complexes bearing κ3C,S,C ligands

Abstract : In NHC pincer complexes incorporatig a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.
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Submitted on : Tuesday, April 15, 2014 - 11:23:24 AM
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Jan C. Bernhammer, Gilles Frison, Han Vinh Huynh. Pincer versus Pseudo-Pincer: Isomerism in Palladium(II) Complexes bearing κ3C,S,C ligands. Dalton Transactions, Royal Society of Chemistry, 2014, 43, pp.8591-8594. ⟨10.1039/C4DT01047G⟩. ⟨hal-00979050⟩

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