Mn21Dy Cluster with a Record Magnetization Reversal Barrier for a Mixed 3d/4f Single-Molecule Magnet

Constantina Papatriantafyllopoulou , Wolfgang Wernsdorfer (1) , Kalil A. Abboud , George Christou (2)

1 NEEL - QuantECA - Circuits électroniques quantiques Alpes
2 UF|Chemistry - Department of Chemistry [Gainesville]

A high-oxidation-state (Mn21DyIII)-Dy-III.IV cluster with an unusual structure is reported. It also possesses a record barrier to magnetization reversal for a 3d/4f single molecule magnet (SMM) and provides insight into how the full benefit of lanthanides to the mixed 3d/4f SMM field might be realized.

Domaines: Physique [physics]

Constantina Papatriantafyllopoulou, Wolfgang Wernsdorfer, Kalil A. Abboud, George Christou. Mn21Dy Cluster with a Record Magnetization Reversal Barrier for a Mixed 3d/4f Single-Molecule Magnet. Inorganic Chemistry, 2011, 50 (2), pp.421-423. ⟨10.1021/ic102378u⟩. ⟨hal-00978484⟩