Supramolecular chains of high nuclearity {Mn-25(III)} barrel-like single molecule magnets

Dimosthenis P. Giannopoulos , Annaliese Thuijs , Wolfgang Wernsdorfer (1) , Melanie Pilkington , George Christou (2) , Theocharis C. Stamatalos

1 NEEL - QuantECA - Circuits électroniques quantiques Alpes
2 UF|Chemistry - Department of Chemistry [Gainesville]

The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {Mn-25(III)} barrel-like cluster linked via Na+ cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.

Domaines: Physique [physics]

Dimosthenis P. Giannopoulos, Annaliese Thuijs, Wolfgang Wernsdorfer, Melanie Pilkington, George Christou, et al.. Supramolecular chains of high nuclearity {Mn-25(III)} barrel-like single molecule magnets. Chemical Communications, 2014, 50 (7), pp.779-781. ⟨10.1039/C3CC47094F⟩. ⟨hal-00975209⟩