Fullerene-grafted block copolymers used as compatibilizer in P3HT/PCBM bulk heterojunctions: morphology and photovoltaic performances

Véronique Gernigon 1 Philippe Lévêque 2 Cyril Brochon 3, 4 Jean-Nicolas Audinot 5 Nicolas Leclerc 6 Rony Bechara 2 Fanny Richard 6 Thomas Heiser 2, * Georges Hadziioannou 3, 4, *
* Auteur correspondant
1 Institut d'électronique du solide et des systèmes (Strasbourg)
Univ Strasbourg, Inst Elect Solide & Syst
2 Univ Strasbourg, Inst Elect Solide & Syst
3 LCPO - Laboratoire de Chimie des Polymères Organiques
4 TEAM 4 LCPO
5 Publ Res Ctr Gabriel Lippman - Sci & Anal Mat Dept
6 Univ Strasbourg - Ecole Europ Chim Polym & Mat, Lab Ing
Abstract : The nanostructure of the active layer in polymer/fullerene bulk heterojunction solar cells is known to have a strong impact on the device performances. Controlling the polymer/fullerene blend morphology is therefore particularly important. In this work, a rod-coil block copolymer, based on a regioregular poly(3-hexylthiophene) electron-donor rod block and a C-60-grafted coil block, is used as compatibilizer and its influences on the thin film morphology as well as the photovoltaic performances are investigated. It is shown that a small fraction of compatibilizer can enhance the device performances in an otherwise non-optimized process. At higher fractions or long annealing times however, the fullerene-grafted copolymer is found to behave as a nucleation center and triggers the formation of fullerene crystals.
keyword : SOLAR-CELLS
Type de document :
Article dans une revue
European Physical Journal: Applied Physics, EDP Sciences, 2011, 56 (3), pp.art nb 34107. 〈10.1051/epjap/2011110150〉
Domaine :
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https://hal.archives-ouvertes.fr/hal-00956850
Contributeur : Dominique Richard <>
Soumis le : vendredi 7 mars 2014 - 14:31:29
Dernière modification le : jeudi 11 janvier 2018 - 06:28:09

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Véronique Gernigon, Philippe Lévêque, Cyril Brochon, Jean-Nicolas Audinot, Nicolas Leclerc, et al.. Fullerene-grafted block copolymers used as compatibilizer in P3HT/PCBM bulk heterojunctions: morphology and photovoltaic performances. European Physical Journal: Applied Physics, EDP Sciences, 2011, 56 (3), pp.art nb 34107. 〈10.1051/epjap/2011110150〉. 〈hal-00956850〉

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