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Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures

Florence Bally 1 Christophe A. Serra 1, * Cyril Brochon 2, 3 Georges Hadziioannou 2, 3
* Corresponding author
1 Ecole nationale supérieure de chimie, polymères et materiaux de strasbourg (ECPM)
2 LCPO - Laboratoire de Chimie des Polymères Organiques
3 Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
LCPO - Laboratoire de Chimie des Polymères Organiques
Abstract : Polymerization reactions can benefit from continuous-flow microprocess in terms of kinetics control, reactants mixing or simply efficiency when high-throughput screening experiments are carried out. In this work, we perform for the first time the synthesis of branched macromolecular architecture through a controlled/living' polymerization technique, in tubular microreactor. Just by tuning process parameters, such as flow rates of the reactants, we manage to generate a library of polymers with various macromolecular characteristics.
Keywords : atom transfer radical polymerization (ATRP) branched continuous-flow microprocess self-condensing vinyl copolymerization (SCVCP)
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https://hal.archives-ouvertes.fr/hal-00956834
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Submitted on : Friday, March 7, 2014 - 1:42:07 PM
Last modification on : Monday, March 28, 2022 - 1:02:04 PM

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Florence Bally, Christophe A. Serra, Cyril Brochon, Georges Hadziioannou. Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures. Macromolecular Rapid Communications, Wiley-VCH Verlag, 2011, 32 (22), pp.1820-1825. ⟨10.1002/marc.201100429⟩. ⟨hal-00956834⟩

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