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Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures

Abstract : Polymerization reactions can benefit from continuous-flow microprocess in terms of kinetics control, reactants mixing or simply efficiency when high-throughput screening experiments are carried out. In this work, we perform for the first time the synthesis of branched macromolecular architecture through a controlled/living' polymerization technique, in tubular microreactor. Just by tuning process parameters, such as flow rates of the reactants, we manage to generate a library of polymers with various macromolecular characteristics.
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https://hal.archives-ouvertes.fr/hal-00956834
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Submitted on : Friday, March 7, 2014 - 1:42:07 PM
Last modification on : Tuesday, May 12, 2020 - 11:04:04 AM

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Florence Bally, Christophe A. Serra, Cyril Brochon, Georges Hadziioannou. Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures. Macromolecular Rapid Communications, Wiley-VCH Verlag, 2011, 32 (22), pp.1820-1825. ⟨10.1002/marc.201100429⟩. ⟨hal-00956834⟩

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