Influence of solubilizing agents (cyclodextrin or surfactant) on phenanthrene degradation by electro-Fenton process - study of soilwashing recycling possibilities and environmental impact.

Abstract : One of the aims in soil washing treatment is to reuse the extracting agent and to remove the pollutant in the meantime. Thus, electro-Fenton (EF) degradation of synthetic soil washing solutions heavily loaded with phenanthrene was suggested for the first time. Two solubilising agents hydroxypropyl-beta-cyclodextrin (HPCD) and Tween 80® (TW 80) were chosen as cyclodextrin (CD) and surfactant representatives, respectively. In order to reuse HPCD and to degrade the pollutant simultaneously, the following optimal parameters were determined: [Fe2+] = 0.05 mM (catalyst), I = 2000 mA, and natural solution pH (around 6), without any adjustment. Only 50% of TW 80 (still higher than the critical micelle concentration (CMC)) can be reused against 90% in the case of HPCD while phenanthrene is completely degraded in the meantime, after only 180 min of treatment. This can be explained by the ternary complex formation (Fe2+-HPCD-organic pollutant) (equilibrium constant K = 56 mM−1) that allows radical dotOH to directly degrade the contaminant. This confirms that Fe2+ plays an important role as a catalyst since it can promote formation of hydroxyl radicals near the pollutant and minimize HPCD degradation. After 2 h of treatment, HPCD/phenanthrene solution got better biodegradability (BOD5/COD = 0.1) and lower toxicity (80% inhibition of luminescence of Vibrio fischeri bacteria) than TW 80/phenanthrene (BOD5/COD = 0.08; 99% inhibition of V. fischeri bacteria). According to these data, HPCD employed in this integrated (soil washing + EF degradation) approach gave promising results in order to be reused whereas the pollutant is degraded in the meanwhile.
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Water Research, IWA Publishing, 2014, 48, pp.306-316. <10.1016/j.watres.2013.09.044>
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https://hal.archives-ouvertes.fr/hal-00925286
Contributeur : Gilles Guibaud <>
Soumis le : mardi 7 janvier 2014 - 18:26:00
Dernière modification le : vendredi 23 mai 2014 - 14:59:43

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E. Mousset, Nihal Oturan, Eric Van Hullebusch, Gilles Guibaud, G. Esposito, et al.. Influence of solubilizing agents (cyclodextrin or surfactant) on phenanthrene degradation by electro-Fenton process - study of soilwashing recycling possibilities and environmental impact.. Water Research, IWA Publishing, 2014, 48, pp.306-316. <10.1016/j.watres.2013.09.044>. <hal-00925286>

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