Polyterpenes by ring opening metathesis polymerization of caryophyllene and humulene

Abstract : Ring opening metathesis polymerization of the natural sesquiterpenes caryophyllene and humulene, optionally complemented by exhaustive post-polymerization hydrogenation, yields non-crosslinked linear polymers with unprecedented microstructures reflecting the specific scaffolds of the feedstocks and with low glass transition temperatures in the range from -15 to -50 degrees C.
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https://hal.archives-ouvertes.fr/hal-00915247
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Submitted on : Friday, December 6, 2013 - 6:35:34 PM
Last modification on : Thursday, January 11, 2018 - 6:28:09 AM

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Etienne Grau, Stefan Mecking. Polyterpenes by ring opening metathesis polymerization of caryophyllene and humulene. Green Chemistry, Royal Society of Chemistry, 2013, 15 (5), pp.1112-1115. ⟨10.1039/c3gc40300a⟩. ⟨hal-00915247⟩

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