Viscosity measurements for squalane at high pressures to 350 MPa from T = (293.15 to 363.15) K - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Chemical Thermodynamics Année : 2014

Viscosity measurements for squalane at high pressures to 350 MPa from T = (293.15 to 363.15) K

Résumé

Squalane is being recommended as a secondary reference material for viscometry at moderate to high pressure and at moderate viscosity. As part of this work, a correlation has been developed for atmospheric pressure (Comuñas et al., 2013) [12]. Here we report new experimental high pressure viscosities for squalane (176 data points obtained for temperatures (293.15 to 363.15) K, at pressures up to 350 MPa with a maximum viscosity of 745 mPa * s). These have been determined with four different falling-body viscometers as well as a quartz crystal resonator viscometer. A preliminary high pressure viscosity correlation for squalane is proposed, based on our new data. At pressures up to 350 MPa, this correlation provides an absolute average deviation of 1.5% with a maximum absolute deviation of 8.9%. Comparison is made between the different instruments. In addition, we have also considered the validity of a thermodynamic scaling model.
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Dates et versions

hal-00903924 , version 1 (13-11-2013)

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Maria J.P. Comuñas, X. Paredes, F.M. Gacino, Josefa Fernandez, Jean-Patrick Bazile, et al.. Viscosity measurements for squalane at high pressures to 350 MPa from T = (293.15 to 363.15) K. Journal of Chemical Thermodynamics, 2014, 69, pp.201. ⟨10.1016/j.jct.2013.10.001⟩. ⟨hal-00903924⟩

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