Synthesis and characterization of iron, iron oxide and iron carbide nanostructures

Ron Snovski (1) , Judith Grinblat (1) , Moulay Tahar Sougrati (2) , Jean-Claude Jumas (2) , Shlomo Margel (1)

1 Institute of Nanotechnology & Advanced Materials, Department of Chemistry, Bar Ilan University, 52900 Ramat Gan, Israel
2 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier

Magnetic iron oxide (Fe3O4 and γ-Fe2O3) and iron carbide (Fe3C) nanoparticles of different geometrical shapes: cubes, spheres, rods and plates, have been prepared by thermal decomposition of a mixture containing the metal precursor Fe(CO)5 and the stabilizer polyvinylpyrrolidone (PVP) at 300 1C in a sealed cell under inert atmosphere. The thermal decomposition process was performed for 4 or 24 h at ([PVP]/[Fe(CO)5]) (w/v) ratio of 1:1 or 1:5. Elemental iron nanospheres embedded within a mixture of amorphous and graphitic carbon coating were obtained by hydrogen reduction of the prepared iron oxide and iron carbide nanoparticles at 450 1C. The formation of the graphitic carbon phase at such a low temperature is unique and probably obtained by catalysis of the elemental iron nanoparticles. Changing the annealing time period and the ([PVP]/[Fe(CO)5]) ratio allowed control of the composition, size, size distribution, crystallinity, geometrical shape and magnetic properties of the different magnetic nanoparticles.

Domaines: Matériaux

Ron Snovski, Judith Grinblat, Moulay Tahar Sougrati, Jean-Claude Jumas, Shlomo Margel. Synthesis and characterization of iron, iron oxide and iron carbide nanostructures. Journal of Magnetism and Magnetic Materials, 2014, 349, pp.35-44. ⟨10.1016/j.jmmm.2013.08.043⟩. ⟨hal-00881788⟩