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Article Dans Une Revue Chemistry - A European Journal Année : 2013

Ruthenium-containing phosphinesulfonate chelate for the hydrogenation of aryl ketones.

Résumé

Various ruthenium(II) complexes that contain phosphinesulfonate chelate have been synthesized. Arene-free complexes were found to be efficient in the base-free hydrogenation of various aryl ketones, whereas the arene-containing precatalysts required the presence of an amine as an additive. The seminal asymmetric hydrogenation reaction by using the new Sulfo-Binepine ligand was also investigated for the possible intervention of a dihydride species.
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Dates et versions

hal-00879887 , version 1 (20-06-2022)

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Fan Jiang, Kedong Yuan, Mathieu Achard, Christian Bruneau. Ruthenium-containing phosphinesulfonate chelate for the hydrogenation of aryl ketones.. Chemistry - A European Journal, 2013, 19 (31), pp.10343-52. ⟨10.1002/chem.201301201⟩. ⟨hal-00879887⟩
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