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Lattice of Partly Permanent Dipoles

Abstract : The electric susceptibility of a lattice of partly permanent dipoles is determined as a function of the temperature and molecular parameters. The calculation is based on the spherical model approximation. The susceptibility has a discontinuous slope at a critical temperature Tc. Numerical techniques are developed for the evaluation of Tc which may have application elsewhere in the statistical theory of lattices. The theory predicts a critical temperature of 98°K for solid hydrogen bromide which corresponds to a measured value of 89°K.
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R. Toupin, M. Lax. Lattice of Partly Permanent Dipoles. Journal of Chemical Physics, American Institute of Physics, 1957, 27 (2), pp.458-464. ⟨hal-00851887⟩

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