MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

J. Canivet (1) , S. Aguado (1) , Y. Schuurman (1) , D. Farrusseng (1)

1 INGENIERIE - INGENIERIE

The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.

Domaines: Catalyse; Chimie organique

J. Canivet, S. Aguado, Y. Schuurman, D. Farrusseng. MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification. Journal of the American Chemical Society, 2013, 135 (11), pp.4195-4198. ⟨10.1021/ja312120x⟩. ⟨hal-00826367⟩