Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles

G. Compain (1) , A. Martin-Mingot (1) , G. Frapper (1) , M.P. Jouannetaud (1) , S. Thibaudeau (1)

1 Chimie de l'eau et traitement de l'eau

Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium-carbenium superelectrophiles in this original process.

Domaines: Catalyse; Chimie organique; Autre

G. Compain, A. Martin-Mingot, G. Frapper, M.P. Jouannetaud, S. Thibaudeau. Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles. Chemical Communications, 2012, 48 (47), pp.5877-5879. ⟨10.1039/c2cc32246c⟩. ⟨hal-00820212⟩