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A new hybrid organic-inorganic chain: [(phen)Cu-μ-(κ2O:O'-VP2O10H3)2-Cu(phen)]n.

Abstract : The structure of the title compound, poly[(dihydrogenphosphato-κO)(μ(3)-hydrogenphosphato)di-μ-oxido-(1,10-phenanthroline)copper(II)vanadium(V)], [CuV(HPO(4))(H(2)PO(4))O(2)(C(12)H(8)N(2))](n), is defined by [(phen)Cu-μ-(κ(2)O:O'-VP(2)O(10)H(3))(2)-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they interdigitate through the phen groups via π-π interactions.
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Submitted on : Tuesday, April 16, 2013 - 3:17:30 PM
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Diego Venegas-Yazigi, Andres Vega, Karen Valdes de La Barra, Marianela Saldias, Eric Le Fur. A new hybrid organic-inorganic chain: [(phen)Cu-μ-(κ2O:O'-VP2O10H3)2-Cu(phen)]n.. Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], International Union of Crystallography, 2012, 68 (Pt 7), pp.m200-2. ⟨10.1107/S0108270112026005⟩. ⟨hal-00814100⟩



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